Carbon does not dissolve into the water! It absorbs chemicals from the water (like metals, medicne traces, tanins), but gets saturated pretty quickly, and then it starts releasing the absorbed chemicals into the water again. That's why it needs to be replaced everey 3 or 4 weeks...
As for your filtration: I wouldn't use only carbon! Fill up at least one with biomedia (for biological filtration, to maintain the tank cycle). The other one could be filled with carbon, but that's not necessary: most people only use it when the water is colored too much, or when they have medicated their fish. I think it's all up to you what you want to use in your second filter!
As for your filtration: I wouldn't use only carbon! Fill up at least one with biomedia (for biological filtration, to maintain the tank cycle). The other one could be filled with carbon, but that's not necessary: most people only use it when the water is colored too much, or when they have medicated their fish. I think it's all up to you what you want to use in your second filter!